Temperature-dependent structure changes of complex aluminium hydrides with Rb and Cs as metal cations
نویسندگان
چکیده
منابع مشابه
Electronic structure and electron-phonon interaction in aluminium hydrides
2014 The superconducting transition temperature of high dose H implanted Al samples has been found by Lamoise et al., to be higher than that of pure Al. Since experimental observations indicate the possibility of H ordering, we have studied the changes in the electronic structure and the electron-phonon interaction of pure Al upon formation of A1H and A1H2. For this purpose, the McMillan parame...
متن کاملHydrogen storage in complex metal hydrides
Complex metal hydrides such as sodium aluminohydride (NaAlH4) and sodium borohydride (NaBH4) are solid-state hydrogen-storage materials with high hydrogen capacities. They can be used in combination with fuel cells as a hydrogen source thus enabling longer operation times compared with classical metal hydrides. The most important point for a wide application of these materials is the reversibil...
متن کاملHydrogen-Mediated Metal Transport in Complex Metal Hydrides
Since this discovery, a number of studies have looked at improving the catalytic effects and understanding the role of additives in H2 cycling. However, the mechanism by which NaAlH4 is activated in the presence of a small amount of a transition metal is still not well understood. One of the principle questions is “How do the Al atoms migrate the long distances required during the hydrogenation...
متن کاملConductometric study of the complex formation of Rb+, Cs+, NH4 +, K+, Tl+ and Ag+ ions with several crown ethers in acetonitrile-dimethylsulfoxide and acetonitrile-dimethylformamide binary mixtures
A conductance study of the interaction between Cs+, Rb+, NH4+, K+, T1+ and Ag+ ions and18-crown-6 (18C6), benzo-18-crown-6 (B18C6), dicyclohexyl-18-crown-6 (DC18C6),dicyclohexyl-24-crown-8 (DC24C8), dibenzo-24-crown-8 (DB24C8) in different binarymixtures of acetonitrile (AN) with dimethylsulfoxide (DMSO) and dimethylformamide (DMF)at 25 °C has been carried out. Formation constants of the result...
متن کاملInvestigation of metal hydrides applicability as neutron moderator and shielding by MCNPX
In this research, the applicability of several metal hydrides as neutron moderator and shielding for D-D fusion sources has been investigated by MCNPX code. The results have been investigated in three steps to find the materials with lower thermal, fast and total neutron fluxes than conventional shielding materials. The results show relative advantages of LaNi5H6, VH, TiH2, TaH, Mg (BH4)2, YH2,...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2018
ISSN: 2053-2733
DOI: 10.1107/s2053273318088952